Utilization of waste Cappadocia earth as a natural pozzolan in alkali activation: A parametric study
Küçük Resim Yok
Tarih
2022
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Sci Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
This study presents the investigation of the possible use of rock-cut carving waste earth in Cappadocia as a precursor in alkali activation. The Cappadocia waste earth was activated by sodium hydroxide (NH) and sodium silicate (WG). In addition, slaked lime (CH) was substituted as a calcium resource. The compressive strength development was determined and the reaction mechanisms were investigated through X-ray diffraction and Fourier transform infrared spectroscopy. It was found that different strength levels can be obtained, depending on the activator type and CH-substitution ratio. While WG-activated mixes presented higher early age values, NH-activated mixes presented higher values at further ages, i.e., ~17 MPa at 28 days. The CH substitution enhanced the compressive strength for both early and further ages, attributing to the available Ca2+ ions resulting in the formation of C-A-S-H gel. The XRD results showed that silicates group minerals prominent in control mixes, while C-A-S-H-like gel was the primary phase in CH-substituted mixes. N-A-S-H and other hydrated compounds were found in all mixes, responsible for strength increment. Moreover, secondary electron microscope images revealed a denser structure in WG-activated mixes. Results of energy dispersive spectroscopy and X-ray diffractions corroborated hydration products and alkali activation. The obtained results of this study depict that alkali-activated Cappadocia earth can be a feasible and alternative sustainable binder to be used as a structural material.
Açıklama
Anahtar Kelimeler
Natural Pozzolan, Alkali-Activated Materials, Geopolymers, Cappadocia, Compressive Strength, Microstructure, Inorganic Polymers Geopolymers, Volcanic Ash, Compressive Strength, Engineering Properties, Structural Characteristics, Portland-Cement, Silica Modulus, Microstructure, Binder, Metakaolin
Kaynak
Construction and Building Materials
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
329
